The easy answer is Isaac Newton, but of course, the real answer is more complicated. Though Newton might be better known for his writings on and experiments with gravity and the laws of motion, his prism experiment—the one that proved white light contains many colors—is still rather iconic.
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File:Pointe a Pierre - Trinidad and Tobago.jpg - Wikimedia Commons, pointe de pierre
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File:Pointe a Pierre - Trinidad and Tobago.jpg - Wikimedia Commons, pointe de pierre
A Brief History of the Color Wheel – PRINT Magazine
Who Came Up With the Color Wheel?