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A one-pot method to prepare a multi-metal sulfide/carbon composite

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Because of their high electrochemical activity, good structural stability, and abundant active sites, multi-metal sulfide/carbon (MMS/C) composites are of tremendous interest in diverse fields, including catalysis, energy, sensing, and environmental science. However, their cumbersome, inefficient, and environmentally unfriendly synthesis is hindering their practical application. We report a straightforward and universal method for their production which is based on homogeneous multi-phase interface engineering. The method has enabled the production of 14 different MMS/C composites, as examples, with well-organized composite structures, different components, and dense heterointerfaces. Because of their composition and structure, a typical composite has efficient, fast, and persistent lithium-ion storage. A ZnS-Co<sub>9</sub>S<sub>8</sub>/C composite anode showed a remarkable rate performance and an excellent capacity of 651 mAh·g<sup>−1</sup> at 0.1 A·g<sup>−1</sup> after 600 cycles. This work is expected to pave the way for the easy fabrication of MMS/C composites.

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a) Valence band spectra (the white bar shows d‐band center). b)

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XRD patterns of (a) MIL‐101, (b) MIL‐101‐SO3H, and (c) MIL‐101‐SO3@Cu‐1

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A,B) SEM images of [Zn x Co 1−x S QD@HCP]@rGO composites. Reproduced